Cobalt alkyl complexes of a new family of chiral 1,3-Bis(2-pyridylimino)isoindolates and their application in asymmetric hydrosilylation Désirée C. Sauer, Hubert Wadepohl, and Lutz H. Gade
Erscheinungsform: | Aufsatz |
Autor/Urheber: | |
Beteiligte: | |
Umfang: | 11 |
Anmerkungen: | Gesehen am 13.09.2018 |
Identifikatoren/Sonstige Nummern: | 158094664X [PPN] |
In: | Washington, DC : American Chemical Society, 1962 51(2012), 23, Seite 12948-12958 volume:51 year:2012 number:23 pages:12948-12958 extent:11 |
Inhalt: | - Synopsis: A new family of chiral 1,3-bis(2-pyridylimino)isoindolate ligands with various substitution patterns was prepared using achiral starting materials. Their cobalt alkyl complexes were synthesized and characterized. The application of this enantiomerically pure compounds in the asymmetric hydrosilylation of ketones was tested giving the corresponding alcohols in high yields and enantioselectivity.
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URL: | http://dx.doi.org/10.1021/ic3020749 |
Weiter im Partnersystem: | https://swb.bsz-bw.de/DB=2.1/PPNSET?PPN=158094664X |