Copper-boxmi complexes as highly enantioselective catalysts for electrophilic trifluoromethylthiolations Qing-Hai Deng, Christoph Rettenmeier, Hubert Wadepohl, and Lutz H. Gade

Erscheinungsform:	Aufsatz
Autor/Urheber:	Deng, Qing-Hai
Beteiligte:	Rettenmeier, Christoph Alexander Wadepohl, Hubert Gade, Lutz H.
Umfang:	5
Anmerkungen:	Published online on December 11, 2013 Gesehen am 15.10.2020
Identifikatoren/Sonstige Nummern:	1735645842 [PPN]
In:	Weinheim : Wiley-VCH, 1995 20(2014), 1, Seite 93-97 volume:20 year:2014 number:1 pages:93-97 extent:5
Inhalt:	The enantioselective trifluoromethylthiolation of β-ketoesters using chiral copper-boxmi complexes as catalysts is reported. A number of α-SCF3-substituted β-ketoesters have been obtained with up to >99 % enantiomeric excess (ee), and the trifluoromethylthiolated products were then transformed diastereoselectively to α-SCF3-β-hydroxyesters with two adjacent quaternary stereocenters.
URL:	https://doi.org/10.1002/chem.201303641
Weiter im Partnersystem:	https://swb.bsz-bw.de/DB=2.1/PPNSET?PPN=1735645842

Moyenne (0 Voter)

Commentaires

Regionalauswahl